Stage-2 MnCl$_{ 2}$ GIC magnetically behaves like a quasi 2D $XY$ antiferromagnet on the triangular lattice. It shows a typical spin glass behavior below the spin freezing temperature $T_{ SG}$ (= 1.1 K). The AC magnetic susceptibility shows a peak at $T$ = $T_{ SG}$ at $H$ = 0. This peak shifts to the low temperature side with increasing $H$, according to the de Almeida-Thouless critical line. We have undertaken an extensive study on the $T$ dependence of specific heat in the absence of an external field $H$ and in the presence of $H$ along the $c$ plane. The magnetic specific heat $C_{ mag}$ at $H$ = 0 shows no anomaly at $T_{ SG}$, but exhibits double broad peaks around 5 K and 41 K. The magnetic specific heat $C_{ mag}$ at $H$ = 0 is described by $C_{ mag} \propto (1/T^{ 2})\exp(-\Delta/T)$ with $\Delta = 1.41 \pm 0.03$ K, while $C_{ mag}$ at $H$ = 10 kOe is proportional to $T$. The entropy due to the broad peak around 5 K is 1/3 of the total entropy. The residual entropy is 63 % of the total entropy because of highly frustrated nature of the system. The magnetic neutron scattering indicates that a short range spin order associated with the incommensurate wave vector $| { \bf Q}_{ incomm}|$ ($= 0.522 \AA^{ -1}$ at 0.45 K) appears below 5 K and remains unchanged down to 63 mK. The in-plane spin correlation length is only 18 $\AA$ at 0.45 K. The low temperature phase below $T_{ SG}$ is a kind of reentrant spin glass phase where the spin glass phase coexists with a short range spin order associated with $| { \bf Q}_{ incomm}|$.

Categories: cond-mat.dis-nn

Specific heat of stage-2 MnCl$_{2}$ graphite intercalation compound: co-existence of spin glass phase and incommensurate short-range spin order