We present a study of the magnetic properties of YNiO$_{ 3}$ in the paramagnetic range, above and below the metal-insulator (MI) transition. The dc susceptibility, $\chi_{ dc}$ (measured up to 1000 K) is a decreasing function of T for $T >$150 K (the N\'{ e}el temperature) and we observe two different Curie-Weiss regimes corresponding to the metallic and insulator phases. In the metallic phase, this behaviour seems to be associated with the small ionic radius of Y% $^{ 3+}$. The value of the Curie constant for T$<$ T$_{ MI}$ allows us to discard the possibility of Ni$^{ 3+}$ localization. An electron spin resonance (ESR) spectrum is visible in the insulator phase and only a fraction of the Ni ions contributes to this resonance. We explain the ESR and $\chi _{ dc}$ behaviour for T $<$ T$_{ MI}$ in terms of charge disproportionation of the type 2Ni$% ^{ 3+}\to $ Ni$^{ 2+}$+Ni$^{ 4+},$ that is compatible with the previously observed structural transition across T$_{ MI}$.
Categories: cond-mat.str-el cond-mat.mtrl-sci