Another condition _sine quâ non_ of progress in this department is the separation of true solar lines from those produced by absorption in our own atmosphere. And here little remains to be done. Thollon's great Atlas[672] was designed for this purpose of discrimination. Each of its thirty-three maps exhibits in quadruplicate a subdivision of the solar spectrum under varied conditions of weather and zenith-distance. Telluric effects are thus made easily legible, and they account wholly for 866, partly for 246, out of a total of 3,200 lines. But the death of the artist, April 8, 1887, unfortunately interrupted the half-finished task of the last seven years of his life. A most satisfactory record, meanwhile, of selective atmospheric action has been supplied by the experiments and determinations of Janssen, Cornu and Egoroff, by Dr. Becker's drawings,[673] and Mr. McClean's photographs of the analysed light of the sun at high, low, and medium altitudes; and the autographic pictures obtained by Mr. George Higgs, of Liverpool, of certain rhythmical groups in the red, emerging with surprising strength near sunset, excite general and well-deserved admiration.[674] The main interest, however, of all these documents resides in the information afforded by them regarding the chemistry of the sun.
The discovery that hydrogen exists in the atmosphere of the sun was made by Ångström in 1862. His list of solar elements published in that year,[675] the result of an investigation separate from, though conducted on the same principle as Kirchhoff's, included the substance which we now know to be predominant among them. Dr. Plücker of Bonn had identified in 1859 the Fraunhofer line F with the green ray of hydrogen, but drew no inference from his observation. The agreement was verified by Ångström; two further coincidences were established; and in 1866 a fourth hydrogen line in the extreme violet (named _h_) was detected in the solar spectrum. With Thalèn, he besides added manganese, titanium, and cobalt to the constituents of the sun enumerated by Kirchhoff, and raised the number of identical rays in the solar and terrestrial spectra of iron to no less than 460.[676]
Thus, when Sir Norman Lockyer entered on that branch of inquiry in 1872, fourteen substances were recognised as common to the earth and sun. Early in 1878 he was able to increase the list provisionally to thirty-three,[677] all except hydrogen metals. This rapid success was due to his adoption of the test of _length_ in lieu of that of _strength_ in the comparison of lines. He measured their relative significance, in other words, rather by their persistence through a wide range of temperature, than by their brilliancy at any one temperature. The distinction was easily drawn. Photographs of the electric arc, in which any given metal had been volatilised, showed some of the rays emitted by it stretching across the axis of the light to a considerable distance on either side, while many others clung more or less closely to its central hottest core. The former "long lines," regarded as certainly representative, were those primarily sought in the solar spectrum; while the attendant "short lines," often, in point of fact, due to foreign admixtures, were set aside as likely to be misleading.[678] The criterion is a valuable one, and its employment has greatly helped to quicken the progress of solar chemistry.