Speculum metal is a mixture of around two-thirds copper and one-third tin, making a white brittle alloy that can be polished to make a highly reflective surface. It was used historically to make different kinds of mirrors from personal grooming aids to optical devices until it was replaced by more modern materials such as metal-coated glass mirrors.
Speculum metal mixtures usually contain two parts copper to one part tin along with a small amount of arsenic, although there are other mixtures containing silver, lead, or zinc. This is about twice the proportion of tin to copper typically used in bronze alloys. Archaeologists and others prefer to call it "high-tin bronze", although this broad term is also used for other alloys such as bell metal, which is typically around 20% tin.
Large speculum metal mirrors are hard to manufacture, and the alloy is prone to tarnish, requiring frequent re-polishing. However, it was the only practical choice for large mirrors in high-precision optical equipment between the mid-17th and mid-19th centuries, before the invention of glass silvering.
Speculum metal was noted for its use in the metal mirrors of reflecting telescopes, and famous examples of its use were Newton's telescope, the Leviathan of Parsonstown, and William Herschel's telescope used to discover the planet Uranus. A major difficulty with its use in telescopes is that the mirrors could not reflect as much light as modern mirrors and would tarnish rapidly.
Early history
The knowledge of making very hard white high luster metal out of bronze-type high-tin alloys may date back more than 2000 years in China, although it could also be an invention of western civilizations. Remarks in Pliny the Elder may refer to it. It was certainly in use by the European Middle Ages, giving better reflectivity than the usual bronze mirrors, and tarnishing more slowly. However, tin was expensive, and the composition of the alloy had to be controlled precisely. Confusingly, mirrors made of speculum metal were known at the time, and often later, as "steel mirrors", although they had no steel in them.
It was not suitable for "cold-working" techniques such as repoussé and chasing, being much too hard, but worked well if cast into small objects, and was also used for "Dark Age belt fittings, buckles, brooches" and similar small items, giving an attractive silver-white colouring.
Use in telescopes
Speculum metal found an application in early modern Europe as the only known good reflecting surface for mirrors in reflecting telescopes. In contrast to household mirrors, where the reflecting metal layer is coated on the back of a glass pane and covered with a protective varnish, precision optical equipment like telescopes needs first surface mirrors that can be ground and polished into complex shapes such as parabolic reflectors. For nearly 200 years speculum metal was the only mirror substance that could perform this task. One of the earliest designs, James Gregory’s Gregorian telescope could not be built because Gregory could not find a craftsman capable of fabricating the complex speculum mirrors needed for the design.
Isaac Newton was the first to successfully build a reflecting telescope in 1668. His first reflecting telescope (a design which came to be known as a Newtonian reflector) had a 33-mm (1.3-inch) diameter speculum metal primary mirror of his own formulation. Newton was likewise confronted with the problem of fabricating the complex parabolic shape needed to create the image, but simply settled on a spherical shape. The composition of speculum metal was further refined and went on to be used in the 1700s and 1800s in many designs of reflecting telescopes. The ideal composition was around 68.21% copper to 31.7% tin; more copper made the metal more yellow, more tin made the metal more blue in color. Ratios with up to 45% tin were used for resistance to tarnishing.