We study the single electron model of a semi-infinite graphene sheet interfaced with the vacuum and terminated along a zigzag edge. The model is a Schroedinger operator acting on $L^2(\mathbb{ R}^2)$: $H^\lambda_{ \rm edge}=-\Delta+\lambda^2 V_\sharp$, with a potential $V_\sharp$ given by a sum of translates an atomic potential well, $V_0$, of depth $\lambda^2$, centered on a subset of the vertices of a discrete honeycomb structure with a zigzag edge. We give a complete analysis of the low-lying energy spectrum of $H^\lambda_{ \rm edge}$ in the strong binding regime ($\lambda$ large). In particular, we prove scaled resolvent convergence of $H^\lambda_{ \rm edge}$ acting on $L^2(\mathbb{ R}^2)$, to the (appropriately conjugated) resolvent of a limiting discrete tight-binding Hamiltonian acting in $l^2(\mathbb{ N}_0;\mathbb{ C}^2)$. We also prove the existence of { \it edge states}: solutions of the eigenvalue problem for $H^\lambda_{ \rm edge}$ which are localized transverse to the edge and pseudo-periodic (propagating or plane-wave like) parallel to the edge. These edge states arise from a "flat-band" of eigenstates the tight-binding Hamiltonian.
Categories: math.AP cond-mat.mes-hall cond-mat.mtrl-sci math-ph math.MP quant-ph