The various simple gases which constitute ordinary coal gas do not all burn together in the flame; the temperature required to effect their ignition being lower for some of them than for others. Thus, hydrogen is the first to burn, taking fire readily as soon as it issues from the burner; while the combustion of the heavy hydrocarbons does not commence until they enter the hotter portions of the flame, and is not completed until they reach its farthest extremity. Neither is the process of combustion in both cases the same. The former gas is at once completely consumed; the latter first undergo decomposition by the heat of the flame, being resolved into their elements--hydrogen and carbon--before being fully consumed. This decomposition of the hydrocarbons is a factor of supreme importance in the development of the lighting power of the flame. The hydrogen they contain, being more easily ignited than the carbon, burns first; and the latter is set free, in the solid form, as minute particles of soot. These particles of solid carbon, being liberated in the midst of the flame, are immediately subjected to its most intense heat; they thus become white-hot before they reach the outer verge of the flame, and come in contact with sufficient oxygen to effect their complete combustion. The amount of light developed by any coal-gas flame is directly proportional to the degree of intensity to which the temperature of these carbon particles is raised, and the length of time they remain in the flame before being finally consumed. It becomes, therefore, a matter of considerable importance to know the conditions which are most conducive to the early liberation in the flame of free carbon, and the attainment by it of an exalted temperature.
Looking at the flame (say) of a common slit burner, it is seen to be divided into two sharply defined and wholly distinct portions. First, there is--immediately surrounding the burner head, and extending to some distance from it--a dark, transparent area, which, on closer examination, is found to consist of unignited gas enclosed in a thin envelope of bright blue flame. Second, there is (beyond this central area) a zone, or belt, of brightly luminous flame, white and opaque; the latter property indicating the presence of solid matter at this part of the flame. That the dark central portion of the flame consists chiefly of unignited gas may be shown in various ways, in addition to the evidence afforded by its complete transparency. Thus, if a small glass tube be taken, and its lower end inserted in the flame at this point, the unburnt gas will pass up the tube, and may be lighted at its upper extremity. A splinter of wood thrust through this portion of the flame is charred first at the two edges of the flame; while, in like manner, a piece of platinum foil remains dull in the centre of the flame, and glows only at the points of contact with the outer air. The presence of solid carbon in the luminous portion of the flame may be shown by inserting therein any cold substance (such as a piece of metal or porcelain), which, reducing the temperature of the heated particles of carbon below the point at which they are consumed, becomes instantly coated on its under surface with a deposit of soot. Or, if the flame be suddenly cooled by gently blowing upon its surface, the same result is brought about; clouds of soot are given off, and the flame "smokes."[3]