Marl is an earthy material rich in carbonate minerals, clays, and silt. When hardened into rock, this becomes marlstone. It is formed in marine or freshwater environments, often through the activities of algae.
Marl makes up the lower part of the cliffs of Dover, and the Channel Tunnel follows these marl layers between France and the United Kingdom. Marl is also a common sediment in post-glacial lakes, such as the marl ponds of the northeastern United States.
Marl has been used as a soil conditioner and neutralizing agent for acid soil and in the manufacture of cement.
Description
Marl or marlstone is a carbonate-rich mud or mudstone which contains variable amounts of clays and silt. The term was originally loosely applied to a variety of materials, most of which occur as loose, earthy deposits consisting chiefly of an intimate mixture of clay and calcium carbonate, formed under freshwater conditions. These typically contain 35–65% clay and 65–35% carbonate. The term is today often used to describe indurated marine deposits and lacustrine (lake) sediments which more accurately should be named 'marlstone'.
Marlstone is an indurated (resists crumbling or powdering) rock of about the same composition as marl. This is more correctly described as an earthy or impure argillaceous limestone. It has a blocky subconchoidal fracture, and is less fissile than shale. The dominant carbonate mineral in most marls is calcite, but other carbonate minerals such as aragonite or dolomite may be present.
Glauconitic marl is marl containing pellets of glauconite, a clay mineral that gives the marl a green color. Glauconite is characteristic of sediments deposited in marine conditions.
Occurrences
The lower stratigraphic units of the chalk cliffs of Dover consist of a sequence of glauconitic marls followed by rhythmically banded limestone and marl layers. Such alternating cycles of chalk and marl are common in Cretaceous beds of northwestern Europe. The Channel Tunnel follows these marl layers between France and the United Kingdom. Upper Cretaceous cyclic sequences in Germany and marl–opal-rich Tortonian-Messinian strata in the Sorbas Basin related to multiple sea drawdown have been correlated with Milankovitch orbital forcing.
Marl as lacustrine sediment is common in post-glacial lake-bed sediments. Chara, a macroalga also known as stonewort, thrives in shallow lakes with high pH and alkalinity, where its stems and fruiting bodies become calcified. After the alga dies, the calcified stems and fruiting bodies break down into fine carbonate particles that mingle with silt and clay to produce marl. Marl ponds of the northeastern United States are often kettle ponds in areas of limestone bedrock that become poor in nutrients (oligotrophic) due to precipitation of essential phosphate. Normal pond life is unable to survive, and skeletons of freshwater molluscs such as Sphaerium and Planorbis accumulate as part of the bottom marl.
In Hungary, Buda Marl is found that was formed in the Upper Eocene era. It lies between layers of rock and soil and may be defined it as both "weak rock and strong soil."
Economic geology
Marl has been used as a soil conditioner and neutralizing agent for acid soil and in the manufacture of Portland cement. Because some marls have a very low permeability, they have been exploited for construction of the Channel Tunnel between England and France and are being investigated for the storage of nuclear waste.
Historical use in agriculture
Marl is one of the oldest soil amendments used in agriculture. In addition to increasing available calcium, marl is valuable for improving soil structure and decreasing soil acidity and thereby making other nutrients more available. It was used sporadically in Britain beginning in prehistoric times and its used was mentioned by Pliny the Elder in the 1st century. Its more widespread use from the 16th century on contributed to the early modern agricultural revolution. However, the lack of a high-energy economy hindered its large-scale use until the Industrial Revolution.
Marl was used extensively in Britain, particularly in Lancashire, during the 18th century. The marl was normally extracted close to its point of use, so that almost every field had a marl pit, but some marl was transported greater distances by railroad. However, marl was gradually replaced by lime and imported mineral fertilizers early in the 19th century. A similar historical pattern was seen in Scotland.