The point of maximum energy of chemical action varies as much for different preparations as the scale of action. In the greater number of cases the point of deepest blackening lies about the lower edge of the indigo rays, though in no two cases is it exactly the same, and in many substances it is widely different. On paper prepared with the juice of the ten-week stock (Mathiola annua) there are two maxima, one in the mean yellow and a weaker in the violet; and on a preparation of tartrate of silver Sir John Herschel found three, one in the least refrangible blue, one in the indigo, and a third beyond the visible violet. The decrease in photographic energy is seldom perfectly alike on both sides of the maximum. Thus at the most refrangible end of the solar spectrum the greatest chemical power is exerted in most instances where there is least light and heat, and even in the space where both sensibly cease.
Not only the intensity but the kind of action is different in the different points of the solar spectrum, as evidently appears from the various colours that are frequently impressed on the same analyzing surface, each ray having a tendency to impart its own colour. Sir John Herschel obtained a coloured image of the solar spectrum on paper prepared according to Mr. Talbot’s principle, from a sunbeam refracted by a glass prism and then highly condensed by a lens. The photographic image was rapidly formed and very intense, and, when withdrawn from the spectrum and viewed in common daylight, it was found to be coloured with sombre but unequivocal tints imitating the prismatic colours, which varied gradually from red through green and blue to a purplish black. After washing the surface in water, the tints became more decided by being kept a few days in the dark—a phenomenon, Sir John observes, of constant occurrence, whatever be the preparation of the paper, provided colours are produced at all. He also obtained a coloured image on nitrate of silver, the part under the blue rays becoming a blue brown, while that under the violet had a pinkish shade, and sometimes green appeared at the point corresponding to the least refrangible blue. Mr. Hunt found on a paper prepared with fluoride of silver that a yellow line was impressed on the space occupied by the yellow rays, a green band on the space under the green rays, an intense blue throughout the space on which the blue and indigo rays fell, and under the violet rays a ruddy brown appeared; these colours remained clear and distinct after being kept two months.