The magnetic field and temperature dependencies of the magnetic moments of superconducting crystals of ${ \rm V_{ 3}Si}$ have been studied. In a constant magnetic field and at temperatures somewhat below the superconducting transition temperature, the moments are hysteretic in temperature. However the magnetic moment-magnetic field isotherms are reversible and exhibit features that formally resemble the pressure-volume isotherms of the liquid-gas transition. This suggests the existence of a first-order phase transition, a two-phase regime, and a critical point in the superconducting phase diagram. The entropy change, determined from the data using the Clausius-Clapeyron equation, is consistent with estimates based on the difference in the vortex densities of the two phases.
Categories: cond-mat.supr-con