The periodic law, based as it is on the solid and wholesome ground of experimental research, has been evolved independently of any conception as to the nature of the elements. It does not in the least originate in the idea of an unique matter, and it has no historical connection with that relic of the torments of classical thought; and therefore it affords no more indication of the unity of matter or of the compound nature of the elements than do the laws of Avogadro, and Gerhardt, or the law of specific heats, or even the conclusions of spectrum analysis. None of the advocates of a unique matter has ever tried to explain the law from the standpoint of ideas taken from a remote antiquity, when it was found convenient to admit the existence of many gods—and of a unique matter.
The reader who desires a fuller exposition of the principles of the periodic law must be referred to special treatises on the subject, or to the larger manuals on general chemistry. It must, however, be stated that, while many facts discovered since the original promulgation of the principle and since its development by Lothar Meyer, Carnelley, Thomsen, and others, are consistent with the law, other facts, some of which were known before 1870, are apparently out of harmony with it, or at all events await a fuller interpretation. For example, tellurium is not in its proper place in the scheme if its atomic weight, 127.5, has been correctly ascertained. Cobalt (58.97) and nickel (58.68) have atomic weights so closely accordant that their properties and those of their corresponding compounds should be very similar, and, in fact, almost identical; but such is not the case. Indeed, it has been said, no prevision of the periodic law would have led to the discovery of nickel. Similar considerations apply to manganese, chromium, and iron; the atomic weights of these elements are less widely different than the differences in their properties and the divergence in their chemical relationships would seem to require. The relative positions of argon and potassium are also not consistent with the law. There are difficulties, too, connected with what we know at present concerning the atomic weights of the so-called rare earth metals. In spite, however, of these seeming anomalies, it can hardly be doubted that the periodic law is as much the expression of a natural law as is the law of gravitation; although it is possible, and indeed probable, that, as we now define it, it is only the first approximation to the truth, and that, as our knowledge becomes more precise, Mendeléeff’s classification, in its present form, will require modification and extension, just as Mendeléeff’s own scheme may be said to be a modification and extension of the attempts at the rational classification of the chemical elements made by his predecessors.