Argon has been found to exist in the gases from springs and mineral waters, notably in those of Bath, Cauterets, Wildbad, and Harrogate. It has also been found in a meteorite, in the gas occluded in rock-salt, and in the minerals _malacone_, _uraninite_, _brōggerite_, etc. No animal or vegetable substance appears to contain it. It is present in atmospheric air to the extent of about one per cent. by volume. It is a colourless gas of an atomic weight of 39.9: one litre of it at the standard temperature and pressure weighs 1.7815 grams. Experiments made by the method of Kundt and Warburg—_i.e._, by determining the ratio of the specific heats at constant pressure and constant volume by the velocity of sound in the gas—prove that argon, like mercury gas, is monatomic. This of itself indicates that argon is an element, since a monatomic compound is a contradiction in terms. The calculations from the experimental data presuppose that argon obeys the laws of Boyle and Dalton, which was found on trial to be the case. By the application of cold and pressure argon can be liquefied. The liquid boils at -186°.1 and freezes at -187°.9. The spectrum of the gas is exceedingly complicated, consisting of a great number of lines extending throughout the visible portion and far into the extreme red and ultra-violet. The colour of the light emitted on sparking the gas changes with increase of temperature from a brilliant red to a bright blue—depending on the intensity of the discharge. All attempts to induce argon to enter into combination with other substances have failed. The methods of its preparation show that it does not combine with oxygen, although Troost and Ouvrard state that it unites with magnesium vapour. It forms no compounds with hydrogen, chlorine, phosphorus, sulphur, sodium, tellurium, etc. Even fluorine, probably the most generally active of the chemical elements, shows no tendency to unite with it.
In 1888 Dr. Hillebrand, of the U.S. Geological Survey, in examining a form of uraninite known as _cleveite_, so named from the late Professor Cleve, found that on treatment with dilute sulphuric acid it gave off considerable quantities of a gas which was assumed to consist only of nitrogen, as it gave the spectroscopic reactions of that element. To test whether this gas contained argon, Ramsay, in 1895, further examined it spectroscopically. After sparking it with oxygen in the presence of caustic soda solution, in the way already described, it gave no indications of argon. The main characteristic of its spectrum was a bright yellow line, known as D3, not coincident with that afforded by sodium, but identical in position with a line detected in the chromosphere during the solar eclipse of 1868, which line, on examination by Frankland and Lockyer, could not be ascribed to any known element. For this supposed new element the name _helium_, from ἥλιος, the sun, had been suggested. This was the first occasion on which an element observed originally only in the sun was found to occur also on the earth. The presence of the new element in the gas from cleveite was subsequently confirmed by Langlet working in Cleve’s laboratory.