_Samarium_ was discovered in 1879 by Lecoq de Boisbaudran in _samarskite_. Its salts are yellow, and afford in solution characteristic absorption bands.
It is not improbable that many of the minerals from which the so-called rare earths are obtained contain elements hitherto unrecognised, and it is possible that certain of the substances now assumed to be elements may, like didymium, turn out to be mixtures. In fact, additional elements have from time to time been announced, as for example, the _decipium_ of Delafontaine (1878) and the _monium_ or _victorium_ of Crookes (1899), pronounced by Urbain to be identical with gadolinium: their individuality cannot as yet be said to be established. Didymium itself was stated by Krüss and Nilson (1888) to be even more complicated than the work of Auer von Welsbach would seem to indicate, and to contain no fewer than eight elementary substances. As yet, however, no confirmation of this surmise has been obtained.
The chemistry of the rare earths has of late years been greatly extended owing to the employment of certain of the members of the group in the manufacture of the “mantles” used in gas-lighting, and which consist substantially of thoria, mixed with about one per cent. of ceria. Large quantities of _monazite_, _thorianite_, _thorite_, _cerite_, and other minerals, are now worked up for the sake of the thoria and ceria they contain, and considerable amounts of residual products, consisting largely of other members of the family, are now available for investigation. It is reasonably certain, therefore, that our knowledge of this section of inorganic chemistry will be largely augmented in the immediate future. Indeed, the application of thoria to the construction of gas-mantles may be said to have removed that substance from the category of the rare elements. No sooner was it discovered that it was capable of useful application than unexpected sources of supply were found.
The same result has followed in other cases. One of the most significant developments of modern chemistry is seen in the efforts which are constantly being made to turn the so-called rare elements to useful account; and when they are found to be technically valuable it is generally observed that hitherto unknown sources of supply are soon available. Cerium salts have been found to be useful in the colouring of glass and porcelain, as mordants in dyeing, in photography, and in medicine. Zirconium has been used in incandescent electric lighting, and thallium has been employed in the manufacture of highly refractive optical glass. Titanium, molybdenum, and vanadium are used in the manufacture of steel of high tensile strength. Tantalum and tungsten are employed in the construction of filaments in incandescent electric lighting. Tantalum, indeed, has been found to occur in considerable quantities, and to be more largely distributed than was hitherto supposed. Alloys of tungsten and aluminium are used in automobile construction, and alloys of tungsten, aluminium, and copper in the manufacture of propeller blades. Tungsten steel is used in armour plates, and to stiffen the springs of cars; in the manufacture of piano-wire, and to increase the permanency of magnets. Even the rarer metals of the platinum group are finding many important applications. Osmium-iridium is used for the bearings of compasses, for the tips of gold pens, and in the construction of standard weights. Osmium and ruthenium enter into the composition of filaments for electric lighting. The extraordinary influence of light on the electric conductivity of selenium has been made use of in the transmission of photographs by telegraph and telephone wires, and for measuring the light intensity of the Röntgen rays in clinical work.