The fixed point corresponding to the temperature of melting ice is called the _freezing point_. It is obtained by keeping the bulb and the part of the tube occupied by mercury immersed in melting ice, until the mercury contracts to a certain point, where it remains stationary. This position of the end of the mercury is then marked upon the tube.
The _boiling point_ is not so easily determined, for the barometer must be consulted about the same time. The boiling apparatus is generally constructed of copper. It consists of a cylindrical boiler, heated from the base by a spirit lamp or charcoal fire. An open tube two or three inches in diameter and of suitable length enters the top of the boiler. This tube is enveloped by another fixed to the top of the boiler but not opening into it, and so that the two tubes are about an inch apart. The object of the outer tube is to protect the inner tube from the cold temperature of the air. The outer tube has an opening at the top for the admission of the thermometer, and a hole near the bottom for the escape of steam through a spout. When the water is made to boil, the steam rises in the inner tube, fills the space between the tubes, and escapes at the spout. The thermometer is then passed down into the inner cylinder, and held securely from the top by means of a piece of caoutchouc. The tubes or cylinders should be of sufficient length to prevent the thermometer entering the water. This is necessary because the temperature of boiling water is influenced by any substance which it holds in chemical solution; and, moreover, its temperature increases with the depth, owing to the pressure of the upper stratum. The thermometer being thus surrounded with steam, the mercury rises in the tube. As it does so, the tube should be depressed so as always to keep the top of the mercury just perceptible. When the temperature of the vapour is attained, the mercury ceases to rise, and remains stationary. The position of the end of the mercury is now marked upon the tube, and the "_boiling-point_" is obtained.
=57. Methods of ascertaining the exact Boiling Temperature.=--The normal boiling temperature of water all nations have tacitly agreed to fix under a normal barometric pressure of 29·922 inches of mercury, having the temperature of melting ice, in the latitude of 45°, and at the sea-level. If the atmospheric pressure at the time or place of graduating a thermometer does not equal this, the boiling temperature will be higher or lower according as the pressure is greater or less. Hence a reading must be taken from a reliable barometer, which must also be corrected for errors and temperature, and reduced for latitude, in order to compare the actual atmospheric pressure at the time with the assumed normal pressure. Tables of vapour tension, as they are termed, have been computed from accurate experimental investigations and theory,--giving the temperatures of the vapour of water for all probable pressures; Regnault's, the most recent, is considered the most accurate; and his investigations are based upon the standard pressure given above, and are for the same latitude. His Table, therefore, will give the temperature on the thermometric scale corresponding to the pressure.