We first give a short review of the ``local-current approximation'' (LCA), derived from a general variation principle, which serves as a semiclassical description of strongly collective excitations in finite fermion systems starting from their quantum-mechanical mean-field ground state. We illustrate it for the example of coupled translational and compressional dipole excitations in metal clusters. We then discuss collective electronic dipole excitations in C$_{ 60}$ molecules (Buckminster fullerenes). We show that the coupling of the pure translational mode (``surface plasmon'') with compressional volume modes in the semiclasscial LCA yields semi-quantitative agreement with microscopic time-dependent density functional (TDLDA) calculations, while both theories yield qualitative agreement with the recent experimental observation of a ``volume plasmon''.

Categories: physics.atm-clus nucl-th physics.atom-ph physics.flu-dyn

Coupling of Surface and Volume Dipole Oscillations in C-60 Molecules