The remarkable achievements of modern chemistry in connection with coal-tar products do not end with the formation of colouring-matters, medicines, and perfumes. The introduction of the beautiful dyes has had an influence in other directions, and has led to results quite unsuspected until the restless spirit of investigation opened out new fields for their application. A few of these secondary uses are sufficiently important to be chronicled here. In sanitary engineering, for example, the intense colouring power of fluoresceïn is frequently made use of to test the soundness of drains, or to find out whether a well receives drainage from insanitary sources. In photography also coal-tar colouring-matters are playing an important part by virtue of a certain property which some of these compounds possess.
The ordinary photographic plate is, as is well known, much more sensitive to blue and violet than to yellow or red, so that in photographing coloured objects the picture gives a false impression of colour intensity, the violets and blues impressing themselves too strongly, and the yellows and reds too feebly. It was discovered by Dr. H. W. Vogel in 1873 that if the sensitive film is slightly tinted with certain colouring-matters, the sensitiveness for yellow and red can be much increased, so that the picture is a more natural representation of the object. Plates thus dyed are said to be "isochromatic" or "orthochromatic," and by their use paintings or other coloured objects can be photographed with much better results than by the use of ordinary plates. The boon thus conferred upon photographic art is therefore to be attributed to coal-tar chemistry. Among the numerous colouring-matters which have been experimented with, the most effective special sensitizers are erythrosin, one of the phthaleïns, quinoline red, a compound related to the same group, and cyanin, a fugitive blue colouring-matter obtained from quinoline in 1860 by Greville Williams.
In yet another way has photography become indebted to the tar chemist. Two important developers now in common use are coal-tar products, viz. hydroquinone and eikonogen. The history of these compounds is worthy of narration as showing how a product when once given by chemistry to the world may become applicable in quite unexpected directions. Chloroform is a case in point. This compound was discovered by Liebig in 1831, but its use as an anæsthetic did not come about till seventeen years after its discovery. It was Sir James Simpson who in 1848 first showed the value of chloroform in surgical operations. A similar story can be told with respect to these photographic developers.