Cyanogen, formed by passing nitrogen over red-hot carbon, consists of two equivalents of carbon and one of nitrogen. It is a frequent constituent of organic and inorganic compounds, and travels in the voltaic circuit as if it were a simple substance.
Ammonia consists of three equivalents of hydrogen and one of nitrogen; now, when the radical phenyle, which consists of twelve equivalents of carbon and five of hydrogen, is put in the ammonia for one equivalent of hydrogen, the result is aniline, whence most of the coal tar colours are obtained. In like manner carbazotic acid, a beautiful yellow dye from coal tar, is carbolic acid, three of whose equivalents of hydrogen have been replaced by three equivalents of an oxide of nitrogen.
Compound radicles, consisting of carbon and the three elementary gases, have been discovered which enter into combination in definite proportions as simple atoms, and all compound radicles travel in the galvanic circuit as equivalents to the elementary substances. Hitherto they have been regarded as representatives or equivalents of one atom of hydrogen. Now it is generally admitted that each has the property of replacing two, three, or more atoms of hydrogen by equivalent substitution. This multiple equivalency among compound radicals forms the basis of what is called the polyatomic theory, now so much employed by MM. Hofmann, Berthelot, and other great modern chemists.
Water is the most common radicle both in the inorganic and organic world. Though a compound of oxygen and hydrogen, it enters, according to the law of definite proportion, into the composition of various amorphous bodies in a dry state, that is in the form and proportion of its gases. It is an essential element in the greater number of crystals, and abounds in organic matter. In certain cases the same substance crystallizes at different temperatures, unites with different quantities of water under the form of oxygen and hydrogen, and assumes corresponding forms. For example, the seleniate of zinc unites with three different portions of water and takes three different forms, according as its temperature is hot, lukewarm, or cold. Thus each particle of water, containing one atom of oxygen and one of hydrogen, combines with one atom of zinc in three different proportions as if it were a simple atom.