71. Adulterated Canned Fruits.--Analyses of a number of canned fruits, made by various Boards of Health, show the presence of small amounts of arsenic, tin, lead, and other poisonous metals. The quantity dissolved depends upon the kind, age, and condition of the canned goods and the state of the fruit when canned. The longer a can of fruit or vegetable has been kept in stock, the larger is the amount of tin or metal that has been dissolved. When fresh canned, there is usually very little dissolved tin, but in old goods the amount may be comparatively large. The tin used for the can is occasionally of poor quality and may contain some arsenic, which also is dissolved. The occasional use of canned goods preserved in tin is not objectionable, but they should not be used continually if it can be avoided. Preservatives, as borax, salicylic acid, benzoic acid, and sodium sulphate, are sometimes added to prevent fermentation and to preserve the natural appearance of the fruit or vegetable.[18]
72. Fruit Flavors and Extracts.--Formerly all fruit extracts and flavors were obtained from vegetable sources; at present many are made in the chemical laboratory by synthetic methods; that is, by combining simpler organic compounds and radicals to produce the material having the desired flavor and odor. The various fruit flavors are definite chemical compounds, and can be produced in the laboratory as well as in the cells of plants. When properly made, there is no difference in chemical composition between the two. As prepared in the laboratory, however, traces of acids, alkalies, and other compounds, used in bringing about the necessary chemical combination, are often present, not having been perfectly removed. Hence it is that natural and artificial flavors differ mainly in the impurities which the artificial flavors may contain.
Some of the flavoring materials have characteristic medicinal properties, as the flavor of bitter almond, which contains hydrocyanic acid, a poisonous substance. Flavors and extracts should not be indiscriminately used. In small amounts they often exert a favorable influence upon the digestion of foods, and the value of some fruits is in a large measure due to the special flavors they contain. A study of the separate compounds which impart flavor to fruits, as the various aldehydes, ethers, and organic salts, belongs to organic chemistry rather than to foods. Some of the simpler compounds of which flavors are composed may exist in entirely different form or combination in food products; as for example, pineapple flavoring is ethyl butrate. This can be prepared by combination of butyric acid from stale butter with alcohol which supplies the ethyl radical. The chemical union of the two produces the new compound, ethyl butrate, the distinctive flavoring substance of the pineapple. Banana flavor can be made from stale butter, caustic soda, and chloroform. None of these materials, as such, go into the flavor, but an essential radical is taken from each. These manufactured products, when properly made, are in every essential similar to the flavor made by the plant and stored up in the fruit. The plant combines the material in the laboratory of the plant cell, and the manufacturer of essences puts together these same constituents in a chemical laboratory. In the fruit, however, the essential oil is associated with a number of other compounds.