Since aqueous vapour has a very exalted absorbent power, a gas or vapour was rendered perfectly dry before its absorbent capacity was determined. For that purpose the pipe that introduced it into the brass experimental tube was so constructed that the gas had first to pass over fragments of pumice-stone wet with strong sulphuric acid, which absorbed its moisture and dried it. Common atmospheric air, however, was not only dried in this manner, but it was deprived of its carbonic acid by passing over caustic potash, and many other precautions were taken to prevent the possibility of error.

Under the ordinary pressure of the atmosphere, when the experimental tube was exhausted, the needle of the goniometer stood at zero, but as soon as pure dry atmospheric air was introduced into the tube its absorption caused the needle to move from zero to 1°.

On Molecular and Microscopic Science, Volume 1 (of 2) — Part 29

The tube was again exhausted; the needle stood at zero, but was deflected from zero to 1° as soon as the tube was filled with oxygen. A similar experiment was made with nitrogen and hydrogen with the same result. Thus, dry air and the elementary gases, oxygen, nitrogen, and hydrogen, have the same absorptive power, and consequently they all deflected the needle of the goniometer one degree. The whole amount of radiant heat that passed through the exhausted tube produced a deflection of 71° 5ʹ; hence taking as unit of heat the amount that would deflect the needle one degree, the number of units expressed by 71° 5ʹ is 308, consequently the absorption of each of these four gases amounts to 100/308 or 0·3 per cent. The most delicate tests could not show any difference between the three first, but Professor Tyndall had reason to believe that hydrogen has the lowest absorptive power of all gases and vapours, though he was unable to express the amount. The absorptive power of all four is very much less than that of every other gas or vapour, and invariably deflects the needle to 1°, which thus becomes the unit of comparison.

On Molecular and Microscopic Science, Volume 1 (of 2) — Part 29

Olefiant gas, the most luminous of the constituents of coal gas, possesses the highest absorptive power of the permanent gases. When sent into the exhausted tube it deflected the needle of the goniometer from 0° to 70° 3ʹ, which is equivalent to 290 units. The whole heat that passed through the exhausted tube before the gas was admitted produced a deflection of 75° or 360 units, consequently more than 7/10ths or 81 per cent. of the whole heat was cut off by the olefiant gas. Such opacity to heat in so transparent a gas is quite marvellous. A current of it was sent into the open air between the thermo-electric pile and one of the sources of heat, and although it was perfectly invisible, it instantly deflected the needle of the goniometer from 0° to 41°.

On Molecular and Microscopic Science, Volume 1 (of 2) — Part 29