Valero is a surname and a masculine given name. Notable people with the name are as follows:
Surname
Aaron Valero (1913–2000), Israeli physician and educator
Addy Valero (died 2020), Venezuelan politician
Antonio Valero, multiple people
Antonio Valero de Bernabe (1790–1863), Puerto Rican military leader
Art Valero (born 1958), American football coach
Bodil Valero (born 1958), Swedish politician
Borja Valero (born 1985), Spanish football player
Carlos Gimeno Valero (born 2001), Spanish tennis player
Carmen Valero (born 1955), Spanish athlete
Cristina Torrens Valero (born 1974), Spanish tennis player
Cristóbal Valero (1707–1789), Spanish painter and presbyter
Damien Valero (born 1965), French artist and academic
David Valero (born 1988), Spanish cyclist
Dora Martínez Valero (born 1976), Mexican politician
Edwin Valero (1981–2010), Venezuelan professional boxer
Elisa Valero (born 1971), Spanish architect and academic
Elisabet Escursell Valero (born 1996), Spanish cyclist
Haim Aharon Valero (1846–1923), banker and first non-rabbi to lead the Sephardi Kollel in Jerusalem Francisco Valero (1906–1982), Mexican fencer Jacob Valero (1813–1874), Jewish banker Jorge Valero (born 1946), Venezuelan historian and ambassador José Sótero Valero Ruz (1936–2012), Venezuelan Catholic bishop Julien Valéro (born 1984), French football player Julieta Valero (born 1971), Spanish poet Maria Valero (born 1991), Venezuelan volleyball player Mateo Valero (born 1952), Spanish computer architect Óscar Valero (born 1985), Spanish football player Roberto Valero (1955–1994), Cuban poet and novelist Roque Valero (born 1974), Venezuelan singer, actor and politician Rosemary Valero-O'Connell (born 1994), American illustrator and cartoonist Thierry Valéro, French rugby player Xavi Valero (born 1973), Spanish football goalkeeper Ximena Valero (born 1977), Mexican fashion designer