Within the framework of a simple Rouse-type model we present exact analytical results for dynamical critical behaviour on the sol side of the gelation transition. The stress-relaxation function is shown to exhibit a stretched-exponential long-time decay. The divergence of the static shear viscosity is governed by the critical exponent $k=\phi -\beta$, where $\phi$ is the (first) crossover exponent of random resistor networks, and $\beta$ is the critical exponent for the gel fraction. We also derive new results on the behaviour of normal stress coefficients.
Categories: cond-mat.stat-mech cond-mat.dis-nn cond-mat.soft physics.chem-ph