Absolute dating is the process of determining an age on a specified chronology in archaeology and geology. Some scientists prefer the terms chronometric or calendar dating, as use of the word "absolute" implies an unwarranted certainty of accuracy. Absolute dating provides a numerical age or range, in contrast with relative dating, which places events in order without any measure of the age between events.
In archaeology, absolute dating is usually based on the physical, chemical, and life properties of the materials of artifacts, buildings, or other items that have been modified by humans and by historical associations with materials with known dates (such as coins and historical records). For example, coins found in excavations may have their production date written on them, or there may be written records describing the coin and when it was used, allowing the site to be associated with a particular calendar year. Absolute dating techniques include radiocarbon dating of wood or bones, potassium-argon dating, and trapped-charge dating methods such as thermoluminescence dating of glazed ceramics.
In historical geology, the primary methods of absolute dating involve using the radioactive decay of elements trapped in rocks or minerals, including isotope systems from younger organic remains (radiocarbon dating with ) to systems such as uranium–lead dating that allow determination of absolute ages for some of the oldest rocks on Earth.
Radiometric techniques
Radiometric dating is based on the known and constant rate of decay of radioactive isotopes into their radiogenic daughter isotopes. Particular isotopes are suitable for different applications due to the types of atoms present in the mineral or other material and its approximate age. For example, techniques based on isotopes with half-lives in the thousands of years, such as carbon-14, cannot be used to date materials that have ages on the order of billions of years, as the detectable amounts of the radioactive atoms and their decayed daughter isotopes will be too small to measure within the uncertainty of the instruments.
Radiocarbon dating
One of the most widely used and well-known absolute dating techniques is carbon-14 (or radiocarbon) dating, which is used to date organic remains. This is a radiometric technique since it is based on radioactive decay. Cosmic radiation entering Earth's atmosphere produces carbon-14, and plants take in carbon-14 as they fix carbon dioxide. Carbon-14 moves up the food chain as animals eat plants and as predators eat other animals. With death, the uptake of carbon-14 stops.
It takes 5,730 years for half the carbon-14 to decay to nitrogen; this is the half-life of carbon-14. After another 5,730 years, only one-quarter of the original carbon-14 will remain. After yet another 5,730 years, only one-eighth will be left.
By measuring the carbon-14 in organic material, scientists can determine the date of death of the organic matter in an artifact or ecofact.
Limitations
The relatively short half-life of carbon-14, 5,730 years, makes dating reliable only up to about 60,000 years. The technique often cannot pinpoint the date of an archeological site better than historic records but is highly effective for precise dates when calibrated with other dating techniques such as tree-ring dating.
An additional problem with carbon-14 dates from archeological sites is known as the "old wood" problem. It is possible, particularly in dry, desert climates, for organic materials such as dead trees to remain in their natural state for hundreds of years before people use them as firewood or building materials, after which they become part of the archaeological record. Thus, dating that particular tree does not necessarily indicate when the fire burned or the structure was built.
For this reason, many archaeologists prefer to use samples from short-lived plants for radiocarbon dating. The development of accelerator mass spectrometry (AMS) dating, which allows a date to be obtained from a very small sample, has been very useful in this regard.
Potassium-argon dating
Other radiometric dating techniques are available for earlier periods. One of the most widely used is potassium–argon dating (K–Ar dating). Potassium-40 is a radioactive isotope of potassium that decays into argon-40. The half-life of potassium-40 is 1.3 billion years, far longer than that of carbon-14, allowing much older samples to be dated. Potassium is common in rocks and minerals, allowing many samples of geochronological or archeological interest to be dated.