In the same manner may we also explain a similar _phænomenon_, which often presents itself in saturating an alkali with the different acids: the effervescence is less considerable in the first additions of acid, and becomes more violent as the mixture approaches the point of saturation. This appears most evidently in making the _sal diureticus_ or regenerated tartar: The particles of the vegetable acid here employed being always diffused thro' a large quantity of water, are more gradually applied to those of the alkali, and during the first additions are chiefly united to those that are freest of air.[10]
That the fixed alkali, in its ordinary state, is seldom entirely saturated with air, seems to be confirmed by the following experiment.
I exposed a small quantity of a pure vegetable fixed alkali to the air, in a broad and shallow vessel, for the space of two months; after which I found a number of solid crystals, which resembled a neutral salt so much as to retain their form pretty well in the air, and to produce a considerable degree of cold when dissolved in water. Their taste was much milder than that of ordinary salt of tartar; and yet they seemed to be composed only of the alkali, and of a larger quantity of air than is usually contained in that salt, and which had been attracted from the atmosphere: for they still joined very readily with any acid, but with a more violent effervescence than ordinary; and they could not be mixed with the smallest portion of vinegar, or of the sedative salt, without emitting a sensible quantity of air.
As it now appeared that several alkaline substances have an attraction for fixed air, I tried a few experiments to learn the relative strength of their several attractions.
Twenty four grains of magnesia in fine powder were mixed with five ounces of the caustic ley in a small vial, which was immediately corked and shaken frequently for four hours. The ley was then poured off, and the magnesia washed with repeated affusions of water, and dried. It had lost about the half of its weight, and when reduced to a fine powder was readily dissolved by acids with an effervescence which was hardly perceivable: the alkali had therefore extracted its air. I also threw some fresh magnesia into the ley which had been poured off, and thereby rendered it perfectly mild and similar to a solution of salt of tartar; so that it effervesced briskly with acids.